Art

J-GLOBAL ID：201702256792126138   Reference number：17A0565561

Phase-Field Simulation of Polymerization-Induced Phase Separation: II. Effect of Volume Fraction and Mobility of Network Polymer

重合誘起相分離のフェーズフィールドシミュレーション: ネットワーク高分子の体積分率および移動度の影響

Author (5)： Higuchi Takeshi (Department of Chemistry and Chemical Engineering, Yamagata University) ,  Yano Yusuke (Department of Chemistry and Chemical Engineering, Yamagata University) ,  Aita Tadahiro (Department of Chemistry and Chemical Engineering, Yamagata University) ,  Takami Seiichi (Institute of Multidisciplinary Research for Advanced Materials, Tohoku University) ,  Adschiri Tadafumi (World Premier International Research Center, Advanced Institute for Materials Research (WPI-AIMR), Tohoku University)
Material： Journal of Chemical Engineering of Japan  (J Chem Eng Jpn)
Volume： 50  Issue： 2  Page： 79-85(J-STAGE)  Publication year： 2017 
JST Material Number： S0629A  ISSN： 0021-9592  CODEN： JCEJAQ  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *gel ,  macromolecule ,  porosity(property) ,  pore ,  *silicon dioxide ,  *polyethylene oxide ,  *polymerization ,  *phase separation ,  simulation ,  interface(surface) ,  crystal growth ,  mathematical model ,  Gibbs free energy ,  continuity ,  diffusion equation ,  differential equation ,  spinodal decomposition ,  network structure ,  *volume fraction ,  *mobility(ratio) ,  chemical potential ,  scanning electron microscope
Semi thesaurus term： Cahn-Hilliard equation ,  *silica ,  phase field method ,  phase-field simulation ,  *polyethylene glycol ,  macroporous ,  polymer gel ,  volume fraction

Author keywords (10)： Bicontinuous Macroporous Structure ,  Cahn-Hilliard Equation ,  Phase Field Method ,  Polymerization-Induced Phase Separation ,  Spinodal Decomposition ,  Bicontinuous Macroporous Structure ,  Cahn-Hilliard Equation ,  Phase Field Method ,  Polymerization-Induced Phase Separation ,  Spinodal Decomposition

JST classification (3)： Structure and morphology of polymer solids  (CG02022M) ,  Polymerization in general  (CG04010H) ,  Surface chemistry in general  (CB12010J)

Reference (11)：

• Cahn, J. W.; “On Spinodal Decomposition,” Acta Metall., 9, 795-801 (1961)
• Chan, P. K. and A. D. Rey; “Polymerization-Induced Phase Separation. 1. Droplet Size Selection Mechanism,” Macromolecules, 29, 8934-8941 (1996)
• Chan, P. K. and A. D. Rey; “Polymerization-Induced Phase Separation. 2. Morphological Analysis,” Macromolecules, 30, 2135-2143 (1997)
• Doi, M. and A. Onuki; Polymer Physics and Phase Transition Dynamics (Kobunshi Butsuri Soten-i Dainamikusu), p. 88, Iwanami Shoten, Tokyo, Japan (2000)
• Higuchi, T., Y. Yano, T. Aita, S. Takami and T. Adschiri; “Phase-Field Simulation of Polymerization-Induced Phase Separation: I. Effect of Reaction Rate and Coexisting Polymer,” J. Chem. Eng. Japan, 46, 709-715 (2013)

Terms in the title (7)： 重合 ,  誘起 ,  相分離 ,  フェーズフィールドシミュレーション ,  高分子 ,  体積分率 ,  移動度