Art

J-GLOBAL ID：201702279099935972   Reference number：17A0740129

Molecular Design of a Chiral Bronsted Acid with Two Different Acidic Sites: Regio-, Diastereo-, and Enantioselective Hetero-Diels-Alder Reaction of Azopyridinecarboxylate with Amidodienes Catalyzed by Chiral Carboxylic Acid-Monophosphoric Acid

異なる2つの酸性部位を有するキラルなBroensted酸の分子設計: キラルなカルボン酸-一リン酸が触媒するアゾピリジンカルボキシレートとアミドジエンとの位置-,ジアステレオ-,およびエナンチオ-選択的なヘテロDiels-Alder反応

Author (14)： MOMIYAMA Norie (Inst. for Molecular Sci., Aichi, JPN) ,  MOMIYAMA Norie (SOKENDAI (Graduate Univ. for Advanced Studies), Aichi, JPN) ,  TABUSE Hideaki (Tohoku Univ., Sendai, JPN) ,  NODA Hirofumi (Rikkyo Univ., Tokyo, JPN) ,  YAMANAKA Masahiro (Rikkyo Univ., Tokyo, JPN) ,  FUJINAMI Takeshi (Inst. for Molecular Sci., Aichi, JPN) ,  YAMANISHI Katsunori (Inst. for Molecular Sci., Aichi, JPN) ,  IZUMISEKI Atsuto (Inst. for Molecular Sci., Aichi, JPN) ,  IZUMISEKI Atsuto (SOKENDAI (Graduate Univ. for Advanced Studies), Aichi, JPN) ,  FUNAYAMA Kosuke (Tohoku Univ., Sendai, JPN) ,  EGAWA Fuyuki (Tohoku Univ., Sendai, JPN) ,  OKADA Shino (SOSHO, Inc., Osaka, JPN) ,  ADACHI Hiroaki (SOSHO, Inc., Osaka, JPN) ,  TERADA Masahiro (Tohoku Univ., Sendai, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 138  Issue： 35  Page： 11353-11359  Publication year： Sep. 07, 2016 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *active site ,  acidity (property) ,  optical isomerism ,  *Broensted acid ,  *molecular design ,  catalyst ,  *Diels-Alder reaction ,  phosphoric acid ,  catalytic activity ,  hydrogen bond ,  *carboxylate (salt) ,  nitrogen heterocyclic compound ,  azo compound ,  *amide ,  regiospecific reaction ,  stereoselectivity ,  *diastereoselectivity ,  *enantioselectivity ,  *chirality ,  Pyridines ,  *regioselectivity
Semi thesaurus term： *chirality ,  hydrogen bond interaction ,  Pyridines ,  *location-selectivity

JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (6)： 1-(Benzyloxycarbonylamino)-1,3-butadiene ,  2-(2-Carboxy-3-biphenylyl)-6-(triphenylsilyl)-4-hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin 4-oxide ,  2,6-Bis(triphenylsilyl)-4-hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin 4-oxide ,  Dibenzyl diazenedicarboxylate ,  3-(Benzyloxycarbonylamino)-2-[6-(trifluoromethyl)-2-pyridyl]-3,6-dihydropyridazine-1(2H)-carboxylic acid benzyl ester ,  [2-(Benzyloxycarbonyl)-1-[6-(trifluoromethyl)-2-pyridyl]-1,2,3,6-tetrahydropyridazine-3-yl]carbamic acid benzyl ester

Terms in the title (8)： 酸性 ,  キラル ,  Broensted酸 ,  分子設計 ,  カルボン酸 ,  リン酸 ,  触媒 ,  ヘテロDiels-Alder反応