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J-GLOBAL ID：201802221627964356   Reference number：18A0947187

Moderately Flexible Trans-Chelating Diphosphine Ligands Consisting of a Triazine Unit Showing High Ligand Acceleration Effect for Heck Reaction

Heck反応のための高配位子加速効果を示すトリアジン単位からなる適度に柔軟なtrans-キレート化ジホスフィン配位子

Author (6)： Korenaga Toshinobu (Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University) ,  Kowata Ryo (Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University) ,  Kotaki Tomohiro (Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University) ,  Shibasaki Yuji (Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University) ,  Oishi Yoshiyuki (Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University) ,  Shimada Kazuaki (Department of Chemistry and Biological Sciences, Faculty of Science and Engineering, Iwate University)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 91  Issue： 4  Page： 577-584(J-STAGE)  Publication year： 2018 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Heck reaction ,  *ligand effect ,  nitrogen heterocyclic compound ,  chelation ,  *phosphine complex ,  space structure ,  catalytic activity ,  density functional method ,  turnover number ,  palladium complex ,  palladium catalyst ,  conformational transition ,  organophosphorus compound ,  rhodium complex ,  Triazines ,  polyphenol ,  aromatic iodine compound
Semi thesaurus term： Triazines

JST classification (2)： Platinum family element complexes  (CE01100E) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (12)： 2,7-Naphthalenediol ,  Acrylic acid tert-butyl ,  Hydroquinone ,  Catechol ,  Iodobenzene ,  Resorcinol ,  2,2′-(o-Phenylenebisoxy)bis[4-(diphenylphosphino)-6-phenoxy-s-triazine] ,  2,2′-(m-Phenylenebisoxy)bis[4-(diphenylphosphino)-6-phenoxy-s-triazine] ,  2,2′-(p-Phenylenebisoxy)bis[4-(diphenylphosphino)-6-phenoxy-s-triazine] ,  2,2′-[(Naphthalene-2,7-diyl)bisoxy]bis[4-(diphenylphosphino)-6-phenoxy-s-triazine] ,  2-Phenoxy-4,6-dichloro-s-triazine ,  1-Phenyl-3-tert-butoxy-1,3-butadiene

Reference (43)：

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Terms in the title (7)： Heck反応 ,  配位子 ,  加速 ,  トリ ,  アジン ,  キレート化 ,  ジホスフィン