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J-GLOBAL ID：201802224682306602   Reference number：18A0659200

SYNTHETIC STUDIES OF YESSOTOXIN: STEREOSELECTIVE ANNULATION OF THE CD AND JK RING FRAGMENTS BY USING Pd(II)-CATALYZED CYCLIZATION

イエッソトキシンの合成研究 Pd(II)接触環化反応を用いたCDおよびJK環フラグメントの立体選択的アンヌレーション

Author (7)： YOKOYAMA Hajime (Univ. Toyama, Toyama, JPN) ,  MORIYAMA Genki (Univ. Toyama, Toyama, JPN) ,  NISHIDA Kazuki (Univ. Toyama, Toyama, JPN) ,  KUSUMOTO Yasuhiro (Univ. Toyama, Toyama, JPN) ,  TSUGE Kiyoshi (Univ. Toyama, Toyama, JPN) ,  MIYAZAWA Masahiro (Univ. Toyama, Toyama, JPN) ,  HIRAI Yoshiro (Univ. Toyama, Toyama, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 96  Issue： 3  Page： 470-482  Publication year： Mar. 01, 2018 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  shellfish toxin ,  food poisoning ,  *cyclic ether ,  catalytic reaction ,  palladium catalyst ,  palladium complex ,  *annulation ,  Pyrans ,  diarrhetic shellfish toxin
Semi thesaurus term： diarrhetic shellfish toxin ,  Shellfish Poisoning

JST classification (1)： Condensed derivatives of pyrane  (CF07093I)

Substance index (10)： (3R,4S,6R,7S)-4-(tert-Butyldimethylsiloxy)-10-methoxy-3-methyl-3,7:6,10-diepoxy-1-decene ,  (2R,4aα,8aβ)-2α-Vinyl-2-methyl-6-methoxyoctahydropyrano[3,2-b]pyran-3β-ol ,  (2S,4aβ,8aα)-2β-Vinyl-6α-(4-methoxybenzyloxymethyl)-7β-(benzyloxy)octahydropyrano[3,2-b]pyran-3α-ol ,  (Z)-1-[(2R)-3β-[(tert-Butyldimethylsilyl)oxy]-6-methoxytetrahydro-2H-pyran-2α-yl]-3-methyl-5-[(tetrahydro-2H-pyran-2-yl)oxy]-3-pentene-2-ol ,  (Z)-3-Methyl-5-[(2R)-3β-hydroxy-6-methoxytetrahydro-2H-pyran-2α-yl]-2-pentene-1,4-diol ,  2β-(2,5-Dihydroxy-3-pentenyl)-5α-(benzyloxy)-6β-[[(4-methoxybenzyl)oxy]methyl]tetrahydro-2H-pyran-3α-ol ,  2β-Vinyl-5α-(benzyloxy)-6β-[[(4-methoxybenzyl)oxy]methyl]tetrahydro-2H-pyran-3α-ol ,  3α-[(tert-Butyldimethylsilyl)oxy]-5α-(benzyloxy)-6β-[[(4-methoxybenzyl)oxy]methyl]tetrahydro-2H-pyran-2β-ethanol ,  α-[3-[(tert-Butyldimethylsilyl)oxy]-1-propynyl]-3α-[(tert-butyldimethylsilyl)oxy]-5α-(benzyloxy)-6β-[[(4-methoxybenzyl)oxy]methyl]tetrahydro-2H-pyran-2β-ethanol ,  Yessotoxin

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Terms in the title (9)： イエッソトキシン ,  研究 ,  PD ,  環化反応 ,  Cd ,  環 ,  フラグメント ,  立体 ,  アンヌレーション