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J-GLOBAL ID：201802232751274293   Reference number：18A0608066

Catalytic Dearomative Spirocyclization via Gold Carbene Species Derived from Ynamides: Efficient Synthesis of 2-Azaspiro[4.5]decan-3-ones

イナミドからの金カルベン種を経る触媒的脱芳香族スピロ環化:2-アザスピロ[4.5]デカン 3オン類の効率的な合成【Powered by NICT】

Author (5)： Ito Mamoru (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, 169-8555, Japan) ,  Kawasaki Ryosuke (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, 169-8555, Japan) ,  Kanyiva Kyalo Stephen (Global Center for Science and Engineering, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, 169-8555, Japan) ,  Shibata Takanori (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, 169-8555, Japan) ,  Shibata Takanori (ACT-C (Japan) Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama, 332-0012, Japan)
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 24  Issue： 15  Page： 3721-3724  Publication year： 2018 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： An intramolecular catalytic de...

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Thesaurus term： deprotection ,  phenolic compound ,  *gold ,  hydrogenation ,  *catalyst ,  reactivity ,  *carbene ,  alicyclic compound ,  aminocarboxylic acid ,  primary amine
Semi thesaurus term： 共溶媒 ,  脱芳香族化 ,  *スピロ環化 ,  *イナミド , 【Automatic Indexing@JST】

Author keywords (5)： carbenes ,  dearomatization ,  gold ,  spirocyclohexadienones ,  water

JST classification (1)： Complexes of 9 and 10 groups  (CE01050Y)

Substance index (1)： Gabapentin

Terms in the title (7)： イナミド ,  金 ,  カルベン ,  触媒 ,  芳香族 ,  スピロ環化 ,  デカン