Art

J-GLOBAL ID：201802233303333226   Reference number：18A2207036

Crystal Structure of a Supramolecular Complex Built up from Molybdenum(II) Trifluoroacetate and Copper(II) Schiff-Base Components, [{CuL^t-Bu}₂{Mo₂(O₂CCF₃)₄}₃(H₂O)₂]_n, H₂L^t-Bu = 2,3-bis((5-tert-butyl-2-hydroxybenzylidene)amino)-2,3-butenedinitrile

モリブデン(II)トリフルオロアセタートおよび銅(II)Schiff塩基成分から構築された超分子錯体,[{CuL^t-Bu}₂{Mo₂(O₂CCF₃)₄}₃(H₂O)₂]_n,H₂L^t-Bu=2,3-ビス((5-tert-ブチル-2-ヒドロキシベンジリデン)アミノ)-2,3-ブテンジニトリルの結晶構造

Author (6)： HANDA Makoto (Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University) ,  KAMADA Hiroshi (Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University) ,  YOSHIOKA Daisuke (Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University) ,  HIROMITSU Ichiro (Department of Physics and Materials Science, Interdisciplinary Graduate School of Science and Engineering, Shimane University) ,  KASUGA Kuninobu (Department of Chemistry, Interdisciplinary Graduate School of Science and Engineering, Shimane University) ,  MIKURIYA Masahiro (Department of Physics and Materials Science, Interdisciplinary Graduate School of Science and Engineering, Shimane University)
Material： X-Ray Structure Analysis Online (Web)  (X-Ray Struct Anal Online (Web))
Volume： 34  Page： 59-62(J-STAGE)  Publication year： 2018 
JST Material Number： U0031A  ISSN： 1883-3578  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *molybdenum complex ,  *copper complex ,  *complex(substance) ,  chemical synthesis ,  *crystal structure ,  crystal structure analysis ,  X-ray diffraction ,  triclinic system ,  metal ,  metallic bond ,  bridged complex ,  polymer chain ,  molecular structure ,  complex formation ,  *aromatic nitrile ,  *aromatic hydrocarbon ,  ligand ,  chelate compound ,  aromatic amine ,  supermolecule
Semi thesaurus term： metals and alloys / metal bonding ,  polymer structure ,  multidentate ligand ,  monocrystal X-ray diffraction ,  *supramolecular complex

JST classification (2)： Crystal structure of molecular compounds in general  (BK09050T) ,  Molecular compounds  (CE02000C)

Substance index (2)： 2,3-Bis[(2-hydroxy-5-tert-butylbenzylidene)amino]-2-butenedinitrile ,  Trifluoroacetic acid anion

Reference (7)：

• 1. F. A. Cotton, C. A. Murillo, and R. A. Walton, “Multiple Bonds Between Metal Atoms”, 3rd ed., 2005, Springer Science and Business Media, New York.
• 2. W. Mori, S. Takamizawa, C. N. Kato, T. Ohmura, and T. Sato, Microporous Mesoporous Mater., 2004, 73, 31.
• 3. M. Mikuriya, D. Yoshioka, and M. Handa, Coord. Chem. Rev., 2006, 250, 2194.
• 4. M. J. MacLaclan, M. K. Park, and L. K. Thompson, Inorg. Chem., 1996, 35, 5492.
• 5. J.-P. Cao, T. Fang, L.-Z. Fu, L.-L. Zhou, and S.-J. Zhan, Int. J. Hydrogen Energy, 2014, 39, 13972.

Terms in the title (10)： モリブデン ,  トリフルオロアセタート ,  銅 ,  Schiff塩基 ,  構築 ,  分子錯体 ,  H2O ,  ビス ,  TERT ,  結晶構造