Art

J-GLOBAL ID：201802238421346397   Reference number：18A0780674

Site- and Regio-selective Incorporation of Carbon Dioxide into the C(sp²)-Si Bond of Benzosilacyclobutenes

ベンゾシラシクロブテン類のC(sp²)-Si結合への二酸化炭素のサイト選択的および位置選択的挿入

Author (3)： Ishida Naoki (Department of Synthetic Chemistry and Biological Chemistry, Kyoto University) ,  Okumura Shintaro (Department of Synthetic Chemistry and Biological Chemistry, Kyoto University) ,  Murakami Masahiro (Department of Synthetic Chemistry and Biological Chemistry, Kyoto University)
Material： Chemistry Letters  (Chem Lett)
Volume： 47  Issue： 4  Page： 570-572(J-STAGE)  Publication year： 2018 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *polynuclear aromatic compound ,  *silicon heterocyclic compound ,  *carbon dioxide ,  *insertion reaction ,  nickel complex ,  *nickel catalyst ,  C-C bond ,  regiospecific reaction ,  aromatic carboxylic acid ,  reaction mechanism ,  carbene ,  nitrogen heterocyclic compound ,  ligand ,  organosilicon compound ,  regioselective reaction ,  *C-Si bond ,  carbene ligand
Semi thesaurus term： C-C bond formation ,  carbene ligand

Author keywords (3)： Carbon dioxide ,  Nickel ,  Benzosilacyclobutene

JST classification (3)： Addition reaction,elimination reaction  (CF02030M) ,  Organosilicon compounds  (CF08030C) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (8)： 1,5-Cyclooctadiene ,  1,3-Bis(2,6-diisopropylphenyl)-4-imidazoline ,  1,1-Dimethyl-1,2-dihydro-1-silacyclobuta[a]naphthalene ,  2-Methyl-1-naphthoic acid ,  2,2-Dimethyl-2-sila-3-oxaphenanthrene-4(1H)-one ,  2-Methyl-4-fluorobenzoic acid ,  2-Methyl-4-methoxybenzoic acid ,  2,6-Dimethylbenzoic acid

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Terms in the title (4)： Si ,  二酸化炭素 ,  サイト選択 ,  位置選択