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J-GLOBAL ID：201902222285816143   Reference number：19A0490905

Recyclable Polymer-Supported Terpyridine-Palladium Complex for the Tandem Aminocarbonylation of Aryl Iodides to Primary Amides in Water Using NaN3 as Ammonia Equivalent

Ammonia等価体としてNaN3を用いた水中でのヨウ化アリールの第一アミドへの逐次アミノカルボニル化のためのリサイクル可能なポリマー担持テルピリジン-パラジウム錯体【JST・京大機械翻訳】

Author (3)： Suzuka Toshimasa (Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan) ,  Sueyoshi Hiromu (Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan) ,  Ogihara Kazuhito (Department of Chemistry, Biology and Marine Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan)
Material： Catalysts (Web)
Volume： 7  Issue： 4  Page： 107  Publication year： 2017 
JST Material Number： U7154A  ISSN： 2073-4344  Document type： Article
Article type： 原著論文  Country of issue： Switzerland (CHE)  Language： ENGLISH (EN)

Abstract/Point： Primary aromatic amides are va...

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Thesaurus term： *recycle ,  transition metal catalyst ,  nitrile ,  oxime ,  *iodination ,  *carbonylation ,  catalytic activity ,  organic solvent ,  one-pot synthesis ,  hydration ,  *palladium ,  azide(organic) ,  catalyst ,  *palladium complex
Semi thesaurus term： *アミノカルボニル化 , 【Automatic Indexing@JST】

Author keywords (8)： aminocarbonylation ,  azidocarbonylation ,  palladium ,  terpyridine ,  water ,  sodium azide ,  carbon monoxide ,  Staudinger reaction

JST classification (1)： Platinum family element complexes  (CE01100E)

Reference (28)：

• Roy, S.; Roy, S.S.; Gribble, G.W. Metal-catalyzed amidation. Tetrahedron 2012, 68, 9867-9923.
• Matsuda, F. Acrylamide production simplified. Chemtech 1977, 7, 306.
• Opsahl, R. Amide, Fatty Acid, in Encyclopedia of Chemical Technology, 1st ed.; Kroshcitz, J.I., Ed.; Wiley: New York, NY, USA, 1991; Volume 2, pp. 346-356.
• Gao, L.; Ding, J.; Gao, M.; Wang, Z.; Wu, J.; Li, A. Novel and direct transformation of methyl ketones or carbinols to primary amides by employing aqueous ammonia. Org. Lett. 2009, 11, 3810-3813.
• Soai, K.; Ookawa, A.; Hayashi, H. Novel functional group selectivity in reductions with lithium borohydride in mixed solvents containing methanol. J. Chem. Soc. Chem. Commun. 1983, 12, 668-669.

Terms in the title (10)： 等価 ,  NaN3 ,  水中 ,  ヨウ化 ,  アミド ,  逐次 ,  アミノカルボニル化 ,  リサイクル ,  ポリマー担持 ,  パラジウム錯体