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J-GLOBAL ID：201902239351216872   Reference number：19A1314840

Crystal structures, spectroscopic studies and photodenitrosylation reactions of stereoselectively formed dinitrosyl-molybdenum [Mo(bidentate-N,S)₂(NO)₂] complexes with 2-pyrimidinethiolate derivatives

2-ピリミジンチオラート誘導体との立体選択的に形成されたジニトロシル-モリブデン[Mo(二座-N,S)_2(NO)_2]錯体の結晶構造,分光学的研究および光脱ニトロシル化反応【JST・京大機械翻訳】

Author (5)： Ono Kei (Department of Chemistry, Faculty of Science, Kochi University, Akebono-cho 2-5-1, Kochi, Japan) ,  Kitaoka Koji (Department of Chemistry, Faculty of Science, Kochi University, Akebono-cho 2-5-1, Kochi, Japan) ,  Ikeno Suguru (Department of Chemistry, Faculty of Science, Kochi University, Akebono-cho 2-5-1, Kochi, Japan) ,  Yonemura Toshiaki (Department of Chemistry, Faculty of Science, Kochi University, Akebono-cho 2-5-1, Kochi, Japan) ,  Yonemura Toshiaki (Department of Chemistry and Biotechnology, Faculty of Science and Technology, Kochi University, Akebono-cho 2-5-1, Kochi, Japan)
Material： Polyhedron
Volume： 165  Page： 116-124  Publication year： 2019 
JST Material Number： C0301B  ISSN： 0277-5387  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Abstract/Point： For the first time, the cis(NO...

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Thesaurus term： *complex (compound) ,  hydrogen bond ,  visible light ,  *Molybdenum ,  *crystal structure ,  spectrophotometry (analysis) ,  reaction rate ,  *thiolate ,  symmetry ,  nitrosyl complex ,  dinuclear complex ,  characterization ,  absorbance ,  coordinated structure ,  *nitrosylation

Author keywords (5)： Molybdenum-nitrosyl complexes ,  Thiolato complexes ,  Stereoselective formation ,  Geometrical isomer ,  Photodenitrosyl reaction

JST classification (2)： 6A and 7A groups  (CE01080F) ,  Crystal structure of complex of transition metals(excluding iron group)  (BK09030X)

Terms in the title (9)： 誘導体 ,  立体 ,  モリブデン ,  Mo ,  NO ,  錯体 ,  結晶構造 ,  分光学的研究 ,  ニトロシル化