Art

J-GLOBAL ID：201902239948523893   Reference number：19A0810583

Enantio-differentiating hydrogenation of alkyl 3-oxobutanoates over tartaric acid-modified Ni catalyst: Enthalpy-entropy compensation effect as a tool for elucidating mechanistic features

酒石酸修飾Ni触媒上での3-オキソ酪酸アルキルのエナンチオ識別水素化 機構的特徴を解明するためのツールとしてのエンタルピー-エントロピー補償効果【JST・京大機械翻訳】

Author (6)： Osawa Tsutomu (Graduate School of Science and Engineering for Research, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan) ,  Wakasugi Masahiro (Graduate School of Science and Engineering for Research, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan) ,  Kizawa Tomoko (Metek Co. Ltd, Warada-cho, Kamitoba Minami-ku, Kyoto 601-8133, Japan) ,  Borovkov Victor (Department of Chemistry and Biotechnology, School of Science Tallinn University of Technology Akadeemia tee 15, 12618 Tallinn, Estonia) ,  Borovkov Victor (College of Chemistry and Materials Science South-central University for Nationalities 182# Minzu RD, Hongshan District, Wuhan City, Hubei province, 430074, China) ,  Inoue Yoshihisa (Department of Applied Chemistry, Osaka University, Yamada-oka, Suita 565-0871, Japan)
Material： Molecular Catalysis
Volume： 449  Page： 131-136  Publication year： 2018 
JST Material Number： B0605C  ISSN： 2468-8231  Document type： Article
Article type： 原著論文  Country of issue： Netherlands (NLD)  Language： ENGLISH (EN)

Abstract/Point： The enantio-differentiating hy...

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Thesaurus term： differentiation (biology) ,  *catalyst ,  *enthalpy ,  enantiomer ,  low temperature ,  *hydrogenation ,  high temperature ,  reaction temperature ,  *Entropy ,  differential ,  *Nickel ,  enantioselectivity ,  enantiomeric excess ,  temperature range

Author keywords (4)： Enantio-differentiating hydrogenation ,  Alkyl 3-oxobutanoate ,  Tartaric acid-modified nickel powder ,  Enthalpy-entropy compensation

JST classification (2)： Stereochemistry of organic reaction  (CF02130V) ,  Other catalysts  (CB06123Z)

Substance index (1)： Tartaric acid

Terms in the title (11)： 酒石酸 ,  修飾 ,  Ni ,  触媒 ,  3-オキソ酪酸 ,  識別 ,  水素化 ,  ツール ,  エンタルピー ,  エントロピー ,  補償効果