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J-GLOBAL ID：201902248191732045   Reference number：19A1803604

Chiral Magnesium Bisphosphate-Catalyzed Asymmetric Double C(sp³)-H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process

逐次ヒドリド移動/環化プロセスに基づくキラルマグネシウム二リン酸塩触媒不斉二重C(sp3)-H結合官能化【JST・京大機械翻訳】

Author (5)： Mori Keiji (Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Japan) ,  Isogai Ryo (Department of Chemistry, Faculty of Science, Gakushuin University, Japan) ,  Kamei Yuto (Department of Chemistry and Research Center for Smart Molecules, Rikkyo University, Japan) ,  Yamanaka Masahiro (Department of Chemistry and Research Center for Smart Molecules, Rikkyo University, Japan) ,  Akiyama Takahiko (Department of Chemistry, Faculty of Science, Gakushuin University, Japan)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 140  Issue： 20  Page： 6203-6207  Publication year： 2018 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Abstract/Point： Described herein is a chiral m...

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Thesaurus term： *cyclization reaction ,  *catalyst ,  hydride ,  *functionalization ,  *hydride shift ,  *phosphate ,  diphosphate ,  achiral ,  diastereoselectivity ,  *chirality

JST classification (2)： Stereochemistry of organic reaction  (CF02130V) ,  Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P)

Terms in the title (8)： ヒドリド移動 ,  環化 ,  プロセス ,  リン酸塩 ,  触媒 ,  Sp3 ,  H結合 ,  官能化