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J-GLOBAL ID：201902260367720595   Reference number：19A2414515

Room-Temperature Benzylic Alkylation of Benzylic Carbonates: Improvement of Palladium Catalyst and Mechanistic Study

ベンジルカルボナートの室温ベンジルアルキル化 パラジウム触媒の改良と機構研究【JST・京大機械翻訳】

Author (9)： Kuwano Ryoichi (Department of Chemistry, Faculty of Science, Kyushu University, Japan) ,  Kuwano Ryoichi (Center for Molecular Systems (CMS), Kyushu University, Japan) ,  Yokogi Masashi (Department of Chemistry, Faculty of Science, Kyushu University, Japan) ,  Sakai Ken (Department of Chemistry, Faculty of Science, Kyushu University, Japan) ,  Sakai Ken (Center for Molecular Systems (CMS), Kyushu University, Japan) ,  Sakai Ken (International Institute for Carbon-Neutral Energy Research, Kyushu University, Japan) ,  Masaoka Shigeyuki (Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Osaka, Japan) ,  Miura Takashi (Department of Chemistry, Faculty of Science, Kyushu University, Japan) ,  Won Sungyong (Department of Chemistry, Faculty of Science, Kyushu University, Japan)
Material： Organic Process Research & Development  (Org Process Res Dev)
Volume： 23  Issue： 8  Page： 1568-1579  Publication year： 2019 
JST Material Number： W1013A  ISSN： 1083-6160  CODEN： OPRDFK  Document type： Article
Article type： 文献レビュー  Country of issue： United States (USA)  Language： ENGLISH (EN)

Abstract/Point： The palladium catalyst for the...

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Thesaurus term： nucleophilic substitution reaction ,  *palladium catalyst ,  *carbonate ,  complex (compound) ,  *catalyst ,  benzylation ,  substrate (biochemistry) ,  *Alkylation ,  *Palladium ,  intermediate ,  nucleophilic reagent ,  ferrocene ,  carbanion ,  aromatic ketone

Author keywords (5)： palladium ,  benzylic substitution ,  benzyl carbonate ,  active methine ,  (η³-benzyl)metal complex

JST classification (2)： Platinum family element complexes  (CE01100E) ,  Aliphatic carboxylic esters,anhydrides,acid halides,acyl peroxides  (CF03210P)

Substance index (1)： Benzil

Terms in the title (5)： 室温 ,  ベンジル ,  アルキル化 ,  パラジウム触媒 ,  研究