Art

J-GLOBAL ID：201902265585631167   Reference number：19A1861771

ASYMMETRIC SYNTHESIS OF t-BUTYL 3-ALKYL-OXINDOLE-3-CARBOXYLATES VIA CHIRAL PHOSPHORIC ACID-CATALYZED DESYMMETRIZATION OF DI-t-BUTYL 2-ALKYL-2-(2-AMINOPHENYL)MALONATES

キラルなリン酸触媒による2-アルキル-2-(2-アミノフェニルマロン酸ジ-t-ブチルの脱対称化を経由する3-アルキルオキシンドール-3-カルボン酸t-ブチルの不斉合成

Author (8)： ISHIDA Kyoji (Kansai Univ., Osaka, JPN) ,  SHIMIZU Masahiro (Kansai Univ., Osaka, JPN) ,  YAMAI Yu-suke (Kansai Univ., Osaka, JPN) ,  NATSUTANI Itaru (Kansai Univ., Osaka, JPN) ,  UESATO Shinichi (Kansai Univ., Osaka, JPN) ,  UESATO Shinichi (Osaka Univ. Pharmaceutical Sci., Osaka, JPN) ,  NAGAOKA Yasuo (Kansai Univ., Osaka, JPN) ,  SUMIYOSHI Takaaki (Kansai Univ., Osaka, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 99  Issue： 2  Page： 1398-1411  Publication year： May. 01, 2019 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  oxygen heterocyclic compound ,  phosphorus heterocyclic compound ,  *polynuclear aromatic compound ,  Broensted acid ,  acid catalytic reaction ,  carboxylate (ester) ,  dicarboxylic acid ,  aliphatic carboxylic acid ,  aromatic amine ,  *lactam ,  *lactamization ,  substituent effect ,  enantiomer ,  organic catalyst ,  Bronsted acid catalyst ,  *Indoles ,  Malonates ,  Cyclic P-Oxides
Semi thesaurus term： Broensted acid catalyst ,  *indoles ,  malonates ,  Cyclic P-Oxides

JST classification (2)： Condensed derivatives of pyrroles  (CF07077C) ,  Catalytic reactions in general  (CB06080F)

Substance index (11)： Phosphoric acid (aS)-3,3′-bis(2,4,6-triisopropylphenyl)-1,1′-binaphthalene-2,2′-diyl ester ,  1,3-ジ-tert-ブチル2-(2-アミノフェニル)-2-プロピルプロパンジオアート ,  1,3-ジ-tert-ブチル2-(2-アミノフェニル)-2-メチルプロパンジオアート ,  tert-butyl (3S)-2-oxo-3-propyl-1H-indole-3-carboxylate ,  tert-butyl (3S)-3,5-dimethyl-2-oxo-1H-indole-3-carboxylate ,  tert-butyl (3S)-3-ethyl-2-oxo-1H-indole-3-carboxylate ,  tert-butyl (3S)-3-methyl-2-oxo-1H-indole-3-carboxylate ,  tert-butyl (3S)-3-benzyl-2-oxo-1H-indole-3-carboxylate ,  tert-butyl (3S)-5-fluoro-3-methyl-2-oxo-1H-indole-3-carboxylate ,  tert-butyl (3S)-5-methoxy-2-oxo-3-propyl-1H-indole-3-carboxylate ,  tert-butyl (3S)-5-methoxy-3-methyl-2-oxo-1H-indole-3-carboxylate

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Terms in the title (7)： キラル ,  リン ,  酸触媒 ,  フェニルマロン酸 ,  対称 ,  カルボン酸 ,  不斉合成