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J-GLOBAL ID：201902288303271420   Reference number：19A0615292

Polymer-Supported Terpyridine-Palladium Complex for the Allylic Alkylation with Arylboronic Acid in Water

水中におけるアリールボロン酸によるアリルアルキル化用の高分子担持テルピリジン-パラジウム錯体

Author (5)： Suzuka Toshimasa (Department of Chemistry, Biology and Marine Science, University of the Ryukyus) ,  Takayama Naoki (Department of Chemistry, Biology and Marine Science, University of the Ryukyus) ,  Unten Masanori (Department of Chemistry, Biology and Marine Science, University of the Ryukyus) ,  Onda Kaoru (Department of Chemistry, Biology and Marine Science, University of the Ryukyus) ,  Ogihara Kazuhito (Department of Chemistry, Biology and Marine Science, University of the Ryukyus)
Material： Transactions of the Materials Research Society of Japan  (Trans Mater Res Soc Jpn)
Volume： 44  Issue： 1  Page： 41-44(J-STAGE)  Publication year： 2019 
JST Material Number： L4468A  ISSN： 1382-3469  Document type： Proceedings
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： allyl group ,  *alkylation ,  *regiospecific reaction ,  *palladium catalyst ,  *ligand ,  *macromolecule ,  *nitrogen heterocyclic compound ,  complex formation ,  *palladium complex ,  aromatic compound ,  *organic boron acid ,  catalyst ,  homogeneous reaction ,  underwater ,  useful material recovery ,  catalyst regeneration ,  reuse ,  catalytic activity ,  stereochemistry ,  transition metal catalyst
Semi thesaurus term： *arylboronic acid ,  *allylic alkylation ,  *terpyridines ,  homogeneous catalyst ,  polymer ligand ,  reuse ,  recovering catalyst

Author keywords (10)： allylic alkylation ,  palladium ,  terpyridine ,  water ,  phosphine-free ,  allylic alkylation ,  palladium ,  terpyridine ,  water ,  phosphine-free

JST classification (3)： Substitution reaction  (CF02020B) ,  Nobel metal catalysts  (CB06122I) ,  Platinum family element complexes  (CE01100E)

Substance index (1)： Phenylboronic acid

Reference (6)：

• [1] For reviews: (a) J. Tsuji, Acc. Chem. Res., 2, 144-152 (1969); (b) J. Tsuji, Pure Appl. Chem. 54, 197-206 (1982); (c) B. M. Trost, T. R. Verhoeven, In Comprehensive Organometallic Chemistry; G. Wilkinson, F. G. A. Stone, E. W. Abel, Eds.; Pergamon: Oxford, 1982; Vol. 8, pp799-938; (d) R. F. Heck, Palladium Reagents in Organic Synthesis; Academic: New York, 1985; (e) J. Tsuji, J. Organomet. Chem., 300, 281-305 (1986); (f) J. Tsuji, I. Minami, Acc. Chem. Res. 20, 140-145 (1987); (g) G. Gonsiglio, R. M. Waymouth, Chem. Rev. 89, 257- 276 (1989); (h) J. Tsuji, Organic Synthesis with Palladium Compounds; Springer: New York, 1990; (i) J. Tsuji, Palladium Reagents and Catalysts; John Wiley and Sons: Chichester, 1995.
• [2] (a) T. Suzuka, M. Adachi, Y. Nakamoto, and K. Ogihara, Trans. Mater. Res. Soc. Jpn., 40, 77-80 (2015). (b) T. Suzuka, M. Adachi, and K. Ogihara, Trans. Mater. Res. Soc. Jpn., 40, 103-106 (2015). (c) T. Suzuka, H. Sueyoshi, S. Maehara, and H. Ogasawara, Molecules, 20, 9906-9914 (2015). (d) T. Suzuka, M. Adachi, Z.-S. Yang, K. Ogihara, and M. Higa, Trans. Mater. Res. Soc. Jpn., 38, 119-122 (2013). (e) T. Suzuka, H. Sueyoshi, K. Ogihara, Trans. Mater. Res. Soc. Jpn., 41, 225-228 (2016). (f) T. Suzuka, H. Sueyoshi, K. Ogihara, Catalysts, 7, 107-115 (2017).
• [3] T. Suzuka, K. Kimura, T. Nagamine, Polymer, 2, 621-639 (2011).
• [4] (a) For a review of terpyridine-metal complexes, see I. Eryazici, N. Moorefield, and R. Newkome, Chem. Rev., 108, 1834-1895 (2010) and references therein.
• [5] After recycling experiments, ICP-AES analysis showed that leaching of Pd to the aqueous solution occurred at <1 ppm.

Terms in the title (6)： 水中 ,  アリールボロン酸 ,  アリル ,  アルキル化 ,  高分子担持 ,  パラジウム錯体