Art

J-GLOBAL ID：201902296036606128   Reference number：19A2186071

Direct Functionalizations of Carbon-Hydrogen Bonds Catalyzed by Palladium/Bidentate Nitrogen-based Ligand Complexes

パラジウム-窒素系二座配位子錯体触媒を用いる芳香族複素環の炭素-水素結合直接官能基化反応

Author (1)： SHIBAHARA FUMITOSHI (岐阜大学工学部)
Material： 有機合成化学協会誌  (Journal of Synthetic Organic Chemistry, Japan)
Volume： 77  Issue： 8  Page： 776-790(J-STAGE)  Publication year： 2019 
JST Material Number： F0383A  ISSN： 0037-9980  CODEN： YGKKAE  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： JAPANESE (JA)

Thesaurus term： chemical synthesis ,  catalytic reaction ,  *ligand effect ,  palladium catalyst ,  palladium complex ,  *arylation ,  *C-H bond ,  nitrogen heterocyclic compound ,  sulfur heterocyclic compound ,  oxygen heterocyclic compound ,  thiocarbonyl compound ,  oxidative coupling ,  acetylenic compound ,  *alkynylation ,  reaction mechanism ,  polynuclear aromatic compound
Semi thesaurus term： Imidazoles ,  Thioamides ,  bidentate

Author keywords (5)： C-H arylation ,  heterocycles ,  thioamides ,  nitrogen-based ligands ,  palladium catalyst

JST classification (2)： Five-membered heterocyclic compounds in general  (CF07071E) ,  Catalytic reactions in general  (CB06080F)

Substance index (16)： 1,10-Phenanthroline ,  1-Methyl-2-(p-trifluoromethylphenyl)-4,5-dibromo-1H-imidazole ,  1-Methyl-2-(p-tolyl)-4-(p-tolylethynyl)-1H-imidazole ,  1-Methyl-2-(4-methoxyphenyl)-4-phenyl-5-[4-(trifluoromethyl)phenyl]-1H-imidazole ,  1-Methyl-5-[4-(trifluoromethyl)phenyl]-1H-imidazole ,  1-methyl-5-phenyl-2-[4-(trifluoromethyl)phenyl]imidazole ,  1-Benzyl-2-(phenylethynyl)-1H-imidazole ,  N,N-Diisopropyl-2,5-diphenylthiophene-3-carbothioamide ,  2-(4-Methoxyphenyl)-4-[4-(trifluoromethyl)phenyl]-5-phenylthiazole ,  N,N-Diisopropyl-2-phenylthiophene-3-carbothioamide ,  4-(4-methoxyphenyl)-1-methyl-5-phenyl-2-[4-(trifluoromethyl)phenyl]imidazole ,  4-{2-[4-(benzenesulfinyl)-2-methylphenyl]-5-(6-methoxynaphthalen-2-yl)-1-methylimidazol-4-yl}pyridine ,  N,N-diisopropyl-2-[4-(trifluoromethyl)phenyl]thiophene-3-carbothioamide ,  N,N-diisopropyl-3-[4-(trifluoromethyl)phenyl]thiophene-2-carbothioamide ,  N,N-diisopropyl-5-[4-(trifluoromethyl)phenyl]thiophene-2-carbothioamide ,  p-(1-Methyl-4-(p-tolylethynyl)-5-formyl-1H-imidazole-2-yl)benzoic acid ethyl ester

Reference (93)：

• 1) “Heterocyclic Chemistry” eds. by J. A. Joule, K. Mills, 4th ed., Black Science, Oxford, U.K., 2000
• 2) (a) F. Shibahara, A. Kitagawa, E. Yamaguchi, T. Murai, Org. Lett., 8, 5621 (2006)
• (b) F. Shibahara, R. Sugiura, E. Yamaguchi, A. Kitagawa, T. Murai, J. Org. Chem., 74, 3566 (2009)
• (c) F. Shibahara, E. Yamaguchi, A. Kitagawa, A. Imai, T. Murai, Tetrahedron, 65, 5062 (2009)
• (d) S. Tahara, F. Shibahara, T. Maruyama, T. Murai, Chem. Commun., 2009, 7009

Terms in the title (8)： パラジウム ,  窒素 ,  二座配位子 ,  錯体触媒 ,  芳香族複素環 ,  炭素 ,  水素結合 ,  官能基化