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J-GLOBAL ID：201802223039775190   整理番号：18A1073483

酸溶液からの高容量の新しいシアヌル-チオセミカルバジドキレート樹脂へのAg+の選択的吸着【JST・京大機械翻訳】

Selective Adsorption of Ag+ on a New Cyanuric-Thiosemicarbazide Chelating Resin with High Capacity from Acid Solutions

著者 (28件)： Lin Guo (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Lin Guo (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Lin Guo (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Lin Guo (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China) ,  Wang Shixing (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Wang Shixing (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Wang Shixing (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Wang Shixing (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China) ,  Zhang Libo (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Zhang Libo (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Zhang Libo (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Zhang Libo (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China) ,  Hu Tu (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Hu Tu (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Hu Tu (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Hu Tu (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China) ,  Peng Jinhui (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Peng Jinhui (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Peng Jinhui (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Peng Jinhui (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China) ,  Cheng Song (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Cheng Song (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Cheng Song (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Cheng Song (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China) ,  Fu Likang (State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China) ,  Fu Likang (Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China) ,  Fu Likang (Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming 650093, China) ,  Fu Likang (National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming 650093, China)
資料名： Polymers (Web)  (Polymers (Web))
巻： 9  号： 11  ページ： 568  発行年： 2017年 
JST資料番号： U7262A  ISSN： 2073-4360  資料種別： 逐次刊行物 (A)
記事区分： 原著論文  発行国： スイス (CHE)  言語： 英語 (EN)

抄録/ポイント： 新しいシアヌル-チオセミカルバゾン(TSC-CC)キレート樹脂を合成し,酸溶液からAg+を選択的に吸着するために用いた。酸濃度,Ag+の初期濃度,接触時間及び共存イオンの影響を調べた。最適酸濃度は0.5mol/Lであった。Ag+の吸着容量は0.5mol/Lの酸濃度で872.63mg/gに達した。吸着等温線はLangmuir等温モデルと良く適合し,速度データは擬二次モデルに従った。キレート樹脂は酸溶液からのAg+吸着に対して良好な選択性を示した。Fourier変換赤外(FT-IR),X線回折(XRD),走査電子顕微鏡/エネルギー分散分光計(SEM-EDS)およびX線光電子分光法(XPS)を用いて,吸着機構を研究した。キレート化とイオン相互作用は主に吸着機構であった。吸着剤は,高い吸着容量と強い酸性条件の適用の利点により,酸溶液からAg+を選択的に回収する大きな可能性を示した。リサイクル性は,(TSC-CC)樹脂が良好な安定性を有し,Ag+の除去のための有望な薬剤としてリサイクルできることを示した。Copyright 2018 The Author(s). All rights reserved. Translated from English into Japanese by JST.【JST・京大機械翻訳】

シソーラス用語： X線光電子スペクトル ,  吸着剤 ,  接触時間 ,  *吸着 ,  X線回折 ,  分光計 ,  X線光電子分光法 ,  キレート化 ,  相互作用 ,  イオン ,  走査電子顕微鏡 ,  リサイクル ,  吸着等温式
準シソーラス用語： 吸着機構 ,  吸着容量 ,  *キレート樹脂 , 【Automatic Indexing@JST】

著者キーワード (5件)： キレート樹脂 ,  銀イオン ,  選択性 ,  吸着 ,  機構

分類 (2件)： 高分子固体のその他の性質  (CG02025L) ,  吸着,イオン交換  (XD02060I)

引用文献 (30件)：

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• Ying, X.; Li, W.; Jing, X.; Wang, Y.; Xing, Z.; Shan, W.; Lou, Z. Selective recovery of Ag(I) coordination anion from simulate nickel electrolyte using corn stalk based adsorbent modified by ammonia-thiosemicarbazide. J. Hazard. Mater. 2016, 301, 277-285.
• Petrova, Y.S.; Pestov, A.V.; Usoltseva, M.K.; Neudachina, L.K. Selective adsorption of silver(I) ions over copper(II) ions on a sulfoethyl derivative of chitosan. J. Hazard. Mater. 2015, 299, 696-701.
• Wang, J.; Huang, C.P.; Pirestani, D. Interactions of silver with wastewater constituents. Water Res. 2003, 37, 4444-4452.
• Jeon, C. Adsorption of silver ions from industrial wastewater using waste coffee grounds. Korean J. Chem. Eng. 2017, 34, 384-391.

タイトルに関連する用語 (5件)： 酸 ,  溶液 ,  チオセミカルバジド ,  キレート樹脂 ,  選択的吸着