Art

J-GLOBAL ID：200902122943093113   Reference number：02A0920786

First total synthesis and determination of the absolute configuration of strictifolione, a new 6-(ω-phenylalkenyl)-5,6-dihydro-α-pyrone, isolated from Cryptocarya strictifolia.

Cryptocarya strictifoliaから単離された新しい6-(ω-フェニルアルケニル)-5,6-ジヒドロ-α-ピロン,ストリクチホリオンの初全合成及び絶対配置の決定

Author (6)： JULIAWATY L D (Chiba Univ., Chiba, JPN) ,  WATANABE Y (Chiba Univ., Chiba, JPN) ,  KITAJIMA M (Chiba Univ., Chiba, JPN) ,  ACHMAD S A (Inst. Teknologi Bandung, Bandung, IDN) ,  TAKAYAMA H (Chiba Univ., Chiba, JPN) ,  AIMI N (Chiba Univ., Chiba, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 43  Issue： 48  Page： 8657-8660  Publication year： Nov. 25, 2002 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *lactone ,...
Semi thesaurus term： metathesis ,...

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JST classification (2)： Pyranes  (CF07092R) ,  Plant biochemistry  (EH01050J)

Substance index (22)： L-Malic acid ,  (S)-Glycidol ,  (S)-2-Hydroxysuccinic acid diethyl ,  (S)-2-(Trityloxy)succinic acid 1,4-diethyl ester ,  (S)-2-(Trityloxy)-1,4-butanediol ,  (S)-2-(Trityloxy)-4-(tert-butyldiphenylsiloxy)-1-butanol ,  Methanesulfonic acid (S)-2-(trityloxy)-4-(tert-butyldiphenylsiloxy)butyl ester ,  Methanesulfonic acid (S)-2-hydroxy-4-(tert-butyldiphenylsiloxy)butyl ester ,  2β-[2-(tert-Butyldiphenylsilyloxy)ethyl]oxirane ,  2-Phenethyl-1,3-dithiane ,  (S)-1-(2-Phenethyl-1,3-dithiane-2-yl)-4-(tert-butyldiphenylsiloxy)-2-butanol ,  (5S)-1-Phenyl-5-hydroxy-7-(tert-butyldiphenylsiloxy)-3-heptanone ,  (3S,5S)-1-Phenyl-7-(tert-butyldiphenylsiloxy)heptane-3,5-diol ,  (4S)-2,2-Dimethyl-4β-[2-(tert-butyldiphenylsiloxy)ethyl]-6α-phenethyl-1,3-dioxane ,  (4S)-2,2-Dimethyl-6α-phenethyl-1,3-dioxane-4β-ethanol ,  (R)-1-(tert-Butyldiphenylsiloxy)-4-pentene-2-ol ,  Acrylaldehyde isopropyl[(S)-1-(tert-butyldiphenylsiloxymethyl)-3-butenyl]acetal ,  (2R)-2β-(tert-Butyldiphenylsiloxymethyl)-6α-isopropoxy-3,6-dihydro-2H-pyran ,  6α-Isopropoxy-3,6-dihydro-2H-pyran-2β-carbaldehyde ,  (4R)-2,2-Dimethyl-4β-(2-bromoethyl)-6α-phenethyl-1,3-dioxane ,  1-Phenyl-5-[2-[(4R)-2,2-dimethyl-6α-phenethyl-1,3-dioxane-4β-yl]ethylsulfonyl]-1H-tetrazole ,  (4S)-2,2-Dimethyl-4β-[3-[(2R)-6α-isopropoxy-3,6-dihydro-2H-pyran-2β-yl]-2-propenyl]-6α-phenethyl-1,3-dioxane

Terms in the title (5)： Cryptocarya ,  単離 ,  α-ピロン ,  ストリクチホリオン ,  全合成