Art

J-GLOBAL ID：200902206829941138   Reference number：09A0733460

Iodine-Catalyzed Synthesis of Five-Membered Cyclic Ethers from 1,3-Diols under Solvent-Free Conditions

無溶剤の条件下での1,3-ジオールからの5員環エーテルのヨウ素触媒合成

Author (6)： KASASHIMA Yoshio (Education center, Fac. of engineering, Chiba Inst. of Technol.) ,  UZAWA Atsushi (Education center, Fac. of engineering, Chiba Inst. of Technol.) ,  NISHIDA Tadasuke (Graduate School of Sci. and Technol., Chiba Univ.) ,  MINO Takashi (Graduate School of Engineering, Chiba Univ.) ,  SAKAMOTO Masami (Graduate School of Engineering, Chiba Univ.) ,  FUJITA Tsutomu (Graduate School of Engineering, Chiba Univ.)
Material： Journal of Oleo Science  (J Oleo Sci)
Volume： 58  Issue： 8  Page： 421-427 (J-STAGE)  Publication year： 2009 
JST Material Number： G0238A  ISSN： 1345-8957  CODEN： JOSOAP  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *oxygen heterocyclic compound ,  chemical synthesis ,  diol ,  etherification ,  *cyclization reaction ,  iodine ,  catalyst ,  chemical reaction ,  case study ,  solvent-free reaction ,  *Furans
Semi thesaurus term： *furans

JST classification (3)： Condensed derivatives of furan  (CF07073M) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Unit process  (XE01040I)

Substance index (2)： 4a,8a-(Epoxyethano)decalin ,  6-Hydroxyspiro[4.5]decane-6-ethanol

Reference (22)：

• 1. Fujita, T.; Watanabe, S.; Tohtani, M.; Suga, K. A convenient preparation of γ-lactones and dialkyltetrahydrofurans from the reaction of fatty acids with epoxides using lithium naphthalenide. J. Am. Oil Chem. Soc. 61, 1604-1606 (1984).
• 2. Lukevics, E.; Gevorgyan, V.N.; Goldberg, Y.S.; Shymanska, M.V. Synthesis of 3-(2,5-dihydrofural)-silanes and -germanes and their transformations under catalytic hydrogenation conditions. J. Organometallic Chem. 263, 283-296 (1984).
• 3. Eames, J.; Warren, S. Kinetic and thermodynamic control in the stereospecific synthesis of cyclic ethers via phenylsulfanyl migration. Tetrahedron Lett. 37, 3525-3528 (1996).
• 4. Eames, J.; Heras, de las M.A.; Warren, S. Secondary and tertiary alcohols as nucleophiles in the stereospecific synthesis of substituted tetrahydrofurans by cyclization of 1,3-diols with phenylsulfanyl migration. Tetrahedron Lett. 37, 4077-4080 (1996).
• 5. Tamaru, Y.; Yoshida, Z. Heterocyclic synthesis by the use of the oxidizing potential of palladium(II). J. Organometallic Chem. 334, 213-223 (1987).

Terms in the title (5)： 溶剤 ,  ジオール ,  5員環 ,  エーテル ,  ヨウ素触媒