Art

J-GLOBAL ID：200902210711109915   Reference number：09A0213961

Asymmetric 1,3-Dipolar Cycloaddition Reactions of Nitrile Oxides Catalyzed by Chiral Binaphthyldiimine-Ni(II) Complexes

キラルビナフチルジイミン-Ni(II)錯体によって触媒されたニトリルオキシドの不斉1,3-双極環状付加反応

Author (7)： SUGA Hiroyuki (Shinshu Univ., Nagano, JPN) ,  ADACHI Yuki (Shinshu Univ., Nagano, JPN) ,  FUJIMOTO Kouhei (Shinshu Univ., Nagano, JPN) ,  FURIHATA Yasuhisa (Shinshu Univ., Nagano, JPN) ,  TSUCHIDA Teruko (Shinshu Univ., Nagano, JPN) ,  KAKEHI Akikazu (Shinshu Univ., Nagano, JPN) ,  BABA Toshihide (Tokyo Inst. of Technol., Yokohama, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 74  Issue： 3  Page： 1099-1113  Publication year： Feb. 06, 2009 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： diimide ,  *ligand effect ,  nickel complex ,  *nickel catalyst ,  catalytic reaction ,  *1,3-dipolar cycloaddition ,  *nitrile oxide ,  enone ,  *asymmetric synthesis ,  Lewis acid catalyst ,  reaction mechanism ,  PM3 method ,  azomethine ,  modeling ,  molecular structure
Semi thesaurus term： Diimine ,  Naphthalenes ,  molecular modeling

JST classification (6)： Quinolines,isoquinolines  (CF07096H) ,  Naphthalenes  (CF06020D) ,  Cobalt bnd nickel complexes  (CE01092Y) ,  Aromatic monocyclic nitriles,isocyanides  (CF05210D) ,  Alkenes  (CF03030T) ,  Addition reaction,elimination reaction  (CF02030M)

Substance index (17)： 1,1′-Bi[N-(2-quinolylmethylene)naphthalene-2-amine] ,  2,2′-Bis[(4-methyl-2-quinolyl)methyleneamino]-1,1′-binaphthalene ,  2,2′-Bis[(4-phenyl-2-quinolyl)methyleneamino]-1,1′-binaphthalene ,  N,N′-Bis[4-(3,5-xylyl)-2-quinolylmethylene]-1,1′-binaphthalene-2,2′-diamine ,  Mesitonitrile oxide ,  3-Crotonoyloxazolidin-2-one ,  (4S,5S)-3-(2,4,6-Trimethylphenyl)-4-methyl-5-[(2-oxo-3-oxazolidinyl)carbonyl]-4,5-dihydroisoxazole ,  α-Chlorobenzaldehyde oxime ,  Benzonitrile oxide ,  3-Crotonoyl-5,5-dimethyloxazolidine-2-one ,  (4S,5S)-3-Phenyl-4-methyl-5-[(2-oxo-5,5-dimethyl-3-oxazolidinyl)carbonyl]-4,5-dihydroisoxazole ,  1-Benzyl-2-crotonoyl-5,5-dimethylpyrazolidine-3-one ,  2-(3-Phenyl-4α-methyl-2-isoxazoline-5β-ylcarbonyl)-1-benzyl-5,5-dimethylpyrazolidine-3-one ,  3-[(E)-2-Pentenoyl]-5,5-dimethyloxazolidine-2-one ,  3-Phenyl-4-ethyl-5-[(2-oxo-5,5-dimethyl-3-oxazolidinyl)carbonyl]-4,5-dihydroisoxazole ,  1-Benzyl-2-acryloyl-5,5-dimethyl-3-pyrazolidinone ,  (5S)-3-Ethyl-5-[(1-benzyl-3-oxo-5,5-dimethyltetrahydro-1H-pyrazole-2-yl)carbonyl]-4,5-dihydroisoxazole

Terms in the title (5)： Ni ,  錯体 ,  触媒 ,  ニトリルオキシド ,  双極環状付加反応