Art

J-GLOBAL ID：201102280366419864   Reference number：11A0944852

Rhodium-catalyzed Oxidative Coupling of Benzylamines with Alkynes through Dehydrogenation and Dehydrogenative Cyclization

脱水素と脱水素的環化反応によるベンジルアミン類とアルキンとのロジウム触媒酸化的カップリング

Author (4)： MORIMOTO Keisuke (Dep. of Applied Chemistry, Fac. of Engineering, Osaka Univ.) ,  HIRANO Koji (Dep. of Applied Chemistry, Fac. of Engineering, Osaka Univ.) ,  SATOH Tetsuya (Dep. of Applied Chemistry, Fac. of Engineering, Osaka Univ.) ,  MIURA Masahiro (Dep. of Applied Chemistry, Fac. of Engineering, Osaka Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 40  Issue： 6  Page： 600-602 (J-STAGE)  Publication year： 2011 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *Oxidative Coupling ,  catalytic oxidation ,  *rhodium catalyst ,  *cyclization reaction ,  *dehydrogenation (chemical reaction) ,  *amine ,  *aromatic compound ,  acetylenic compound ,  nitrogen heterocyclic compound ,  polynuclear aromatic compound ,  heterocyclic compound ,  rhodium complex ,  cyclopentadienyl complex ,  reaction mechanism ,  aromatic hydrocarbon ,  primary amine ,  Isoindoles ,  Isoquinolines ,  *Benzylamines

JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Aromatic monocyclic amine,imine,quaternary ammonium,immonium compounds  (CF05050D)

Substance index (24)： Diphenylacetylene ,  1-Phenyl-1-propyne ,  1-Phenyl-1-hexyne ,  2-Methylbenzylamine ,  3,4-Diphenylisoquinoline ,  3,4-Diphenyl-6-methylisoquinoline ,  3,4-Diphenyl-8-methylisoquinoline ,  3,4-Diphenylbenzo[h]isoquinoline ,  3,4-Bis(4-chlorophenyl)benzo[h]isoquinoline ,  3,4-Bis(4-methoxyphenyl)benzo[h]isoquinoline ,  3-(1-Butenyl)-3-propyl-3H-benzo[e]isoindole ,  3-Methyl-4-phenylbenzo[h]isoquinoline ,  3-Heptyl-3-(1-octenyl)-3H-benzo[e]isoindole ,  4-Chlorobenzylamine ,  4-Methyl-3-phenylbenzo[h]isoquinoline ,  4-Methylbenzylamine ,  4-Methoxybenzylamine ,  1-Naphthylmethylamine ,  N-(1-Naphthylmethylene)-1-naphthalenemethaneamine ,  Bis(4-chlorophenyl)ethyne ,  1,2-Bis(4-methylphenyl)ethyne ,  Bis(4-methoxyphenyl)acetylene ,  Benzylamine ,  Pentamethylcyclopentadiene

Reference (64)：

• 1) a) T. R. M. Rauws, C. Biancalani, J. W. De Schutter, B. U. W. Maes, Tetrahedron 2010, 66, 6958.
•  b) G. Van Baelen, C. Meyers, G. L. F. Lemière, S. Hostyn, R. Dommisse, L. Maes, K. Augustyns, A. Haemers, L. Pieters, B. U. W. Maes, Tetrahedron 2008, 64, 11802.
•  c) J. E. R. Sadig, M. C. Willis, Synthesis 2011, 1.
•  d) P. Thansandote, M. Lautens, Chem.—Eur. J. 2009, 15, 5874.
•  e) M. Bandini, A. Eichholzer, Angew. Chem., Int. Ed. 2009, 48, 9608.

Terms in the title (6)： 脱水素 ,  環化反応 ,  ベンジルアミン類 ,  アルキン ,  ロジウム触媒 ,  酸化的カップリング