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J-GLOBAL ID：201702243221377406   Reference number：17A1134964

A 1,2-trans-Selective Glycosyl Donor Bearing Cyclic Protection at the C-2 and C-3 Hydroxy Groups

C-2とC-3ヒドロキシル基に環状保護を有する1,2-trans-選択的グリコシル供与体【Powered by NICT】

Author (18)： Yagami Nahoko (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Yagami Nahoko (Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida Ushinomiya-cho, 606-8501, Sakyo-ku, Kyoto, Japan) ,  Tamai Hideki (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Tamai Hideki (Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida Ushinomiya-cho, 606-8501, Sakyo-ku, Kyoto, Japan) ,  Udagawa Taro (Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Ueki Akiharu (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Ueki Akiharu (Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida Ushinomiya-cho, 606-8501, Sakyo-ku, Kyoto, Japan) ,  Konishi Miku (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Konishi Miku (Center for Highly Advanced Integration of Nano and Life Sciences (G-CHAIN), Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Konishi Miku (Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida Ushinomiya-cho, 606-8501, Sakyo-ku, Kyoto, Japan) ,  Imamura Akihiro (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Ishida Hideharu (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Ishida Hideharu (Center for Highly Advanced Integration of Nano and Life Sciences (G-CHAIN), Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Kiso Makoto (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Kiso Makoto (Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida Ushinomiya-cho, 606-8501, Sakyo-ku, Kyoto, Japan) ,  Ando Hiromune (Department of Applied Bioorganic Chemistry, Faculty of Applied Biological Sciences, Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Ando Hiromune (Center for Highly Advanced Integration of Nano and Life Sciences (G-CHAIN), Gifu University, 1-1 Yanagido, 501-1193, Gifu-shi, Gifu, Japan) ,  Ando Hiromune (Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Yoshida Ushinomiya-cho, 606-8501, Sakyo-ku, Kyoto, Japan)
Material： European Journal of Organic Chemistry  (Eur J Org Chem)
Volume： 2017  Issue： 32  Page： 4778-4785  Publication year： 2017 
JST Material Number： W1026A  ISSN： 1434-193X  CODEN： EJOCFK  Document type： Article
Article type： 原著論文  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Abstract/Point： A new 1,2-trans-selective glyc...

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Thesaurus term： carbohydrate ,  glycosylation ,  structure analysis ,  *stereoselectivity ,  *glycoside ,  molecular structure
Semi thesaurus term： conformational search ,  blocking group ,  diastereofacial selectivity ,  Fused-Ring Compounds

Author keywords (6)： Carbohydrates ,  Glycosylation ,  Conformation analysis ,  Protecting groups ,  Diastereoselectivity ,  Glycosides

JST classification (1)： Glycosides  (CF10057O)

Substance index (15)： Phenyl 2-O,3-O-(2,3-dimethoxybutane-2,3-diyl)-4-O,6-O-dibenzyl-1-thio-β-D-glucopyranoside ,  Phenyl 2-O,3-O-(1,1,3,3-tetraisopropylpropanedisiloxane-1,3-diyl)-4-O,6-O-dibenzyl-1-thio-β-D-glucopyranoside ,  Phenyl 2-O,3-O-(o-xylylene)-4-O,6-O-dibenzyl-1-thio-β-D-glucopyranoside ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(2,3-dimethoxybutane-2,3-diyl)-4-O,6-O-dibenzyl-β-D-glucopyranosyl]-α-D-galactopyranose ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(1,1,3,3-tetraisopropylpropanedisiloxane-1,3-diyl)-4-O,6-O-dibenzyl-β-D-glucopyranosyl]-α-D-galactopyranose ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(o-xylylene)-4-O,6-O-dibenzyl-β-D-glucopyranosyl]-α-D-galactopyranose ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-(2-O,3-O,4-O,6-O-tetrabenzyl-β-D-glucopyranosyl)-α-D-galactopyranose ,  Phenyl 2-O,3-O-(o-xylylene)-4-O,6-O-bis(4-methoxybenzyl)-1-thio-β-D-glucopyranoside ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(o-xylylene)-4-O,6-O-bis(4-methoxybenzyl)-β-D-glucopyranosyl]-α-D-galactopyranose ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(o-xylylene)-4-O-benzyl-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranosyl]-α-D-galactopyranose ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(o-xylylene)-4-O-benzyl-6-O-acetyl-β-D-glucopyranosyl]-α-D-galactopyranose ,  1-O,2-O:3-O,4-O-Diisopropylidene-6-O-[2-O,3-O-(o-xylylene)-4-O-(tert-butyldiphenylsilyl)-6-O-benzyl-β-D-glucopyranosyl]-α-D-galactopyranose ,  Butyl 2-O,3-O-(o-xylylene)-4-O,6-O-dibenzyl-β-D-glucopyranoside ,  Benzyl 2-O,3-O-(o-xylylene)-4-O,6-O-dibenzyl-β-D-glucopyranoside ,  (2,2-Dimethyl-1,3-dioxolane-4-yl)methyl 2-O,3-O-(o-xylylene)-4-O,6-O-dibenzyl-β-D-glucopyranoside

Terms in the title (4)： ヒドロキシル基 ,  環状 ,  シル ,  供与体