Art

J-GLOBAL ID：201702277053192728   Reference number：17A0497183

Point-to-Point Ultra-Remote Asymmetric Control with Flexible Linker

フレキシブルリンカによる(Point-to-Point)超遠隔不斉制御

Author (15)： Kawasaki Tsuneomi (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Kawasaki Tsuneomi (Research Center for Chirality, Research Institute for Science and Technology (RIST), Tokyo University of Science, Japan) ,  Kawasaki Tsuneomi (Department of Materials Science and Engineering, University of Fukui, Bunkyo, Fukui, 910-8507, Japan) ,  Ishikawa Yasuyuki (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Minato Yoshihiro (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Otsuka Takashi (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Yonekubo Shigeru (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Sato Itaru (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Sato Itaru (Graduate School of Science and Engineering, Ibaraki University, Bunkyo, Ibaraki, 310-8512, Japan) ,  Shibata Takanori (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Shibata Takanori (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo, 169-8555, Japan) ,  Matsumoto Arimasa (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Matsumoto Arimasa (Research Center for Chirality, Research Institute for Science and Technology (RIST), Tokyo University of Science, Japan) ,  Soai Kenso (Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan) ,  Soai Kenso (Research Center for Chirality, Research Institute for Science and Technology (RIST), Tokyo University of Science, Japan)
Material： Chemistry - European Journal  (Chem Eur J)
Volume： 23  Issue： 2  Page： 282-285  Publication year： 2017 
JST Material Number： W0744A  ISSN： 0947-6539  CODEN： CEUJED  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： autocatalysis ,  asymmetric reaction ,  *addition reaction ,  molecular design ,  Alkylation ,  organosilicon compound ,  diyne ,  nitrogen heterocyclic compound ,  *aldehyde ,  *diol ,  intramolecular interaction ,  linker ,  Pyrimidines ,  Soai reaction
Semi thesaurus term： Pyrimidines ,  aymmetric autocatalysis reaction

Author keywords (5)： 5-pyrimidyl alkanol ,  asymmetric amplification ,  intramolecular stereocontrol ,  remote asymmetric induction ,  stereoselective reaction

JST classification (1)： Stereochemistry of organic reaction  (CF02130V)

Substance index (5)： Diisopropylzinc ,  1,12-Bis[5-[(S)-1-hydroxy-2-methylpropyl]-2-pyrimidinylethynyldimethylsilyl]dodecane ,  1,12-Bis(5-formyl-2-pyrimidinylethynyldimethylsilyl)dodecane ,  1-[5-[(S)-1-Hydroxy-2-methylpropyl]-2-pyrimidinylethynyldimethylsilyl]-19-(5-formyl-2-pyrimidinylethynyldimethylsilyl)nonadecane ,  1-[5-[(S)-1-Hydroxy-2-methylpropyl]-2-pyrimidinylethynyldimethylsilyl]-12-[5-[(R)-1-hydroxy-2-methylpropyl]-2-pyrimidinylethynyldimethylsilyl]dodecane

Terms in the title (1)： リンカ