Research field (2):
Pharmaceuticals - chemistry and drug development
, Synthetic organic chemistry
Research theme for competitive and other funds (10):
2022 - 2027 アニオン安定化置換基の隣接位におけるキラルカルバニオンの発生と捕捉
2016 - 2018 P-キラルホスホニウムを対カチオンとするエナンチオ選択的求核付加反応の開発
2015 - 2017 Development of Enantioselective Synthesis of Allenes Using Chirality Transfer from a Chiral Carbanion
2013 - 2016 Generation of [1,n]-dipolar intermediates and their reactions
2011 - 2012 Enantioselective trapping of an α-chiral carbanion next to conjugating electron-withdrawing groups
2010 - 2012 Generation of multifunctionalized nucleophilic carbenes
2010 - 2012 Enantioselective Synthesis of Allenes by Reduction and a BrookRearrangement
2008 - 2009 Synthetic Studies of Natural Products Containing an Eight-Membered Ring Featuring Tandem Carbon-Carbon Bond Formation.
2007 - 2009 Stereocontrol of Chiral Carbanions in Tandem Reactions
2005 - 2005 エポキシドからの遠隔不斉転写を基盤とするカスケード型中員環形成反応の開発
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Papers (34):
Michiko Sasaki, Akitomo Kasahara, Kei Takeda. Abnormal Michael Reaction: Condition-Dependent Product Distributions in the Michael Reaction of Monoalkyl-Substituted Malonates. The Journal of Organic Chemistry. 2024. 89. 7. 4923-4931
Hidaka Ikemoto, Michiko Sasaki, Misato Fujiwara, Tomo Takegawa, Kei Takeda. Chiral organolithiums next to a conjugative electron-withdrawing group: Their configurational stability and enantioselective trapping by an electrophile. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2011. 242
Michiko Sasaki, Yuri Shirakawa, Eiji Kawanishi, Kei Takeda. ORGN 459-Chirality transfer from epoxide to carbanion: Base-induced alkylation of O-carbamoyl cyanohydrins of beta-silyl-alpha,beta-epoxyaldehyde. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2008. 236
Michiko Sasaki, Hidaka Ikemoto, Mariko Higashi, Kei Takeda. ORGN 458-Trapping of chiral carbanions by [2,3]-Wittig rearrangement. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 2008. 236
Books (1):
Molecular Rearrangements in Organic Synthesis
Wiley 2015
Education (3):
- 2006 Hiroshima University
- 2003 広島大学大学院医 歯薬学総合研究科 博士課程前期
- 2002 Hiroshima University Faculty of Medicine Institute of Pharmaceutical Sciences
Professional career (1):
博士(薬学) (広島大学)
Work history (5):
2019/10 - 現在 Fukushima Medical University
2017/04 - 2018/03 The University of Tokyo Faculty of Pharmaceutical Sciences