Research theme for competitive and other funds (4):
2022 - 2025 Development of ultra-high density bottle-brush polymers by poly(substituted methylene) synthesis
2019 - 2022 Development of multi-component polycondensation of diazocarbonyl compounds
2016 - 2019 Development of new initiating system enabling controlled polymerization of diazoacetate
2014 - 2016 Development of New Polymerization Methods Using Polycondensation of bis(diazocarbonyl) Compounds
Papers (51):
Hiroaki Shimomoto, Takumi Kubo, Kazunari Nishigawa, Hazuki Okuda, Makoto Ishimoto, Tomomichi Itoh, Eiji Ihara. Synthesis of dendronized polymers through Pd-initiated C1 polymerization of diazoacetates with different generation ester-type dendron groups. Polymer Chemistry. 2025
Hiroaki Shimomoto, Shota Inouchi, Tomomichi Itoh, Eiji Ihara. Postpolymerization modification of poly(2-alkoxyethoxycarbonylmethylene)s: Efficient formation and reactivity of the ketene silyl acetal repeating units in the polymer main chain. Polymer Journal. 2024. 56. 6. 569-576
Chikara Kawakami, Mitsuo Hara, Shusaku Nagano, Hiroaki Shimomoto, Yoshitaka Yorimoto, Tomohiro Yamada, Shuichiro Oda, Eiji Ihara, Takahiro Seki. Assembly Structure Formation in Bulk and Ultrathin Films of Poly(substituted methylene) Having an Azobenzene Side Chain. Langmuir. 2024. 40. 21. 11297-11306
Hiroaki Shimomoto, Takaya Izumoto, Kazuki Yamashita, Tomomichi Itoh, Eiji Ihara. A salicylaldiminate/Pd(trifluoroacetate)2 [SalAld/Pd(tfa)2] initiating system for C1 polymerization of diazoacetate: generation of an active initiator from ordinary reagents with facile procedures. Polymer Chemistry. 2024
Hiroaki Shimomoto, Itsuki Katashima, Hirokazu Murakami, Tomomichi Itoh, Eiji Ihara. Effect of the Alkyl Side-Chain Structure on Melting Point of Atactic Poly(alkoxycarbonylmethylene)s: Incorporation of Amide-Linkage Leading to Polymers with High Melting Point. Macromolecules. 2023. 56. 12. 4639-4648
2014/12 - The 10th SPSJ International Polymer Conference Polymer Chemistry Poster Award
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Association Membership(s) (4):
The American Chemical Society
, THE SOCIETY OF SYNTHETIC ORGANIC CHEMISTRY, JAPAN
, THE CHEMICAL SOCIETY OF JAPAN
, THE SOCIETY OF POLYMER SCIENCE, JAPAN