Art

J-GLOBAL ID：200902267241583765   Reference number：04A0677216

EPR Study on Stable Magnesium Complexes of the Phenoxyl Radicals Derived from a Vitamin E Model and Its Deuterated Derivatives

ビタミンEモデルおよびその重水素化誘導体から導かれるフェノキシルラジカルの安定なマグネシウム錯体に関するEPR研究

Author (9)： NAKANISHI I (National Inst. Radiological Sci., Chiba) ,  MATSUMOTO S (Tokyo Metropolitan Inst. Gerontology, Tokyo) ,  OHKUBO K (Osaka Univ., Osaka) ,  FUKUHARA K (National Inst. Health Sci., Tokyo) ,  OKUDA H (National Inst. Health Sci., Tokyo) ,  INAMI K (Kyoritsu Coll. Pharmacy, Tokyo) ,  MOCHIZUKI M (Kyoritsu Coll. Pharmacy, Tokyo) ,  OZAWA T (National Inst. Radiological Sci., Chiba) ,  ITOH S (Osaka City Univ., Osaka)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 77  Issue： 9  Page： 1741-1744  Publication year： Sep. 15, 2004 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *vitamin E ,...
Semi thesaurus term： phenoxyradical

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JST classification (3)： Complexes of nontransition metal elements  (CE01030C) ,  Vitamin E  (EB07060S) ,  Magnetic resonance of complex molecules  (BH06074B)

Substance index (9)： 2,2-Bis(4-tert-octylphenyl)-1-picrylhydrazyl radical ,  Chromanol C1 ,  (2,2,5,7,8-Pentamethylchroman-6-yloxy)radical ,  5-(²H₃)Methyl-2,2,7,8-tetramethyl-3,4-dihydro-2H-1-benzopyran-6-ol ,  [5-(²H₃)Methyl-2,2,7,8-tetramethyl-3,4-dihydro-2H-1-benzopyran-6-yloxy]radical ,  7-(²H₃)Methyl-2,2,5,8-tetramethyl-3,4-dihydro-2H-1-benzopyran-6-ol ,  [7-(²H₃)Methyl-2,2,5,8-tetramethyl-3,4-dihydro-2H-1-benzopyran-6-yloxy]radical ,  8-(²H₃)Methyl-2,2,5,7-tetramethyl-3,4-dihydro-2H-1-benzopyran-6-ol ,  [8-(²H₃)Methyl-2,2,5,7-tetramethyl-3,4-dihydro-2H-1-benzopyran-6-yloxy]radical

Reference (35)：

• 1) L. J. Machlin, “Handbook of Vitamins, Second Edition, Revised and Expanded,” ed by L. J. Machlin, Marcel Dekker, New York (1991), pp. 99–144.
• 2) C. K. Chow, Free Radical Biol. Med., 11, 215 (1991).
• 3) G. W. Burton and K. U. Ingold, Acc. Chem. Res., 19, 194 (1986).
• 4) S. V. Jovanovic, S. Steenken, M. Tosic, B. Marjanovic, and M. G. Simic, J. Am. Chem. Soc., 116, 4846 (1994).
• 5) V. W. Bowry and K. U. Ingold, J. Org. Chem., 60, 5456 (1995).

Terms in the title (7)： ビタミンE ,  モデル ,  重水素化 ,  誘導体 ,  マグネシウム錯体 ,  EPR ,  研究