Art

J-GLOBAL ID：201302210495950181   Reference number：13A1344292

Total synthesis of (+)-azimine via diastereoselective aminopalladation

ジアステレオ選択的アミノパラジウム化を経由する(+)-アジミンの全合成

Author (7)： KUROGOME Yuji (Graduate School of Agriculture, Sciences of Functional Foods, Shinshu Univ., 8304 Minami-minowa, Kami-ina, Nagano ...) ,  KOGISO Masaya (Graduate School of Agriculture, Sciences of Functional Foods, Shinshu Univ., 8304 Minami-minowa, Kami-ina, Nagano ...) ,  LOOI Kok Kong (Dep. of Bioscience and Biotechnology, Fac. of Agriculture, Shinshu Univ., 8304 Minami-minowa, Kami-ina, Nagano ...) ,  HATTORI Yasunao (Dep. of Medicinal Chemistry, Kyoto Pharmaceutical Univ., Yamashina-ku, Kyoto 607-8412, JPN) ,  KONNO Hiroyuki (Dep. of Biochemical Engineering, Graduate School of Sci. and Technol., Yamagata Univ., Yonezawa, Yamagata 992-8510, JPN) ,  HIROTA Mitsuru (Dep. of Bioscience and Biotechnology, Fac. of Agriculture, Shinshu Univ., 8304 Minami-minowa, Kami-ina, Nagano ...) ,  MAKABE Hidefumi (Graduate School of Agriculture, Sciences of Functional Foods, Shinshu Univ., 8304 Minami-minowa, Kami-ina, Nagano ...)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 69  Issue： 39  Page： 8349-8352  Publication year： Sep. 30, 2013 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *alkaloid ,  *metalation ,  allyl compound ,  unsaturated alcohol ,  nitrogen heterocyclic compound ,  metathesis ,  lactonization ,  asymmetric synthesis ,  total synthesis
Semi thesaurus term： *aminopalladation ,  allylic compound ,  *piperidine alkaloid ,  Piperidines ,  macrolactonization ,  cross metathesis

JST classification (1)： Alkaloids  (CF10030D)

Substance index (3)： Azimine ,  6-[1-(Benzyloxycarbonyl)-5α-hydroxy-6α-methylpiperidine-2α-yl]hexanoic acid ,  [(1S,2S)-1-Methyl-2-(methoxymethoxy)-7-hydroxy-5-heptenyl]carbamic acid tert-butyl ester

Terms in the title (2)： ジアステレオ選択 ,  全合成