Art

J-GLOBAL ID：201702245279859222   Reference number：17A0130533

Estimation of σ-Donation and π-Backdonation of Cyclic Alkyl(amino) Carbene-Containing Compounds

環状アルキル(アミノ)カルベン含有化合物のσ-供与およびπ-逆供与の推定

Author (5)： MONDAL Kartik Chandra (Georg-August-Univ., Goettingen, DEU) ,  ROY Sudipta (Georg-August-Univ., Goettingen, DEU) ,  MAITY Bholanath (Indian Inst. of Sci. Education and Res. (IISER) Kolkata, Mohanpur, IND) ,  KOLEY Debasis (Indian Inst. of Sci. Education and Res. (IISER) Kolkata, Mohanpur, IND) ,  ROESKY Herbert W. (Georg-August-Univ., Goettingen, DEU)
Material： Inorganic Chemistry  (Inorg Chem)
Volume： 55  Issue： 1  Page： 163-169  Publication year： Jan. 04, 2016 
JST Material Number： C0566A  ISSN： 0020-1669  CODEN： INOCAJ  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *carbene ,  ring structure ,  donor ,  *coordinate bond ,  nitrogen 15 ,  *chemical shift ,  two-dimensional NMR ,  correlated spectroscopy ,  electron density ,  charge transfer ,  *molecular orbital method ,  density functional method ,  15N NMR ,  *nitrogen heterocyclic compound ,  *back donation ,  NBO analysis

JST classification (2)： Nitrogen heterocycles in general  (CF07040G) ,  Electronic structure of molecules  (BH05010Q)

Substance index (15)： 2-(2,6-Diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]deca-1-ene-2-ium-1-ide ,  2-(2,6-Diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]decane-1-ylideneradical ,  Silicon dichloride ,  2,4,6-Triisopropylphenylphosphine ,  2-(2,6-Diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]deca-1-ene-2-ium ,  [Dichlorosilanediylbis[2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]decane-1,1-diyl]]radical ,  [1,1,2,2-Tetrachlorodisilane-1,2-diylbis[2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]decane-1,1-diyl]]radical ,  9-Isopropyl-1,1,5,5-tetramethyl-9b-aza-4-sila-3a,4,5,9b-tetrahydrospiro[1H-benzo[e]indene-3(2H),1′-cyclohexane] ,  2-(2,6-Diisopropylphenyl)-1-(diphenylphosphino)-3,3-dimethyl-2-azaspiro[4.5]deca-1-ene-2-ium ,  2-(2,6-Diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]decane-1-one ,  [2-(2,6-Diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]deca-1-ene-2-ium]-1-selenol anion ,  Cyclodisilathiane2,4-disulfide ,  Silicon chloride ,  1,2-Dichlorodisilane ,  Disilene

Terms in the title (3)： 環状アルキル ,  カルベン ,  推定