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J-GLOBAL ID：201702263438693277   Reference number：17A1004561

Synthesis and Stereochemical Properties of Chiral Hetero[7]helicenes Structured by a Benzodiheterole Ring Core

ベンゾジヘテロール環コアにより構造化されたキラルヘテロ[7]ヘリセンの合成と立体化学的性質

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Author (13)： Arae Sachie (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Mori Takaaki (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Kawatsu Takahiro (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Ueda Daiki (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Shigeta Yusuke (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Hamamoto Nobutsugu (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Fujimoto Hitoshi (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University) ,  Sumimoto Michinori (Graduate School of Science and Technology for Innovation, Yamaguchi University) ,  Imahori Tatsushi (Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science) ,  Igawa Kazunobu (Institute for Materials Chemistry and Engineering, Kyushu University) ,  Tomooka Katsuhiko (Institute for Materials Chemistry and Engineering, Kyushu University) ,  Punniyamurthy Tharmalingam (Department of Chemistry, Indian Institute of Technology Guwahati) ,  Irie Ryo (Department of Chemistry, Faculty of Advanced Science and Technology, Kumamoto University)
Material： Chemistry Letters  (Chem Lett)
Volume： 46  Issue： 8  Page： 1214-1216(J-STAGE)  Publication year： 2017 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *polynuclear aromatic hydrocarbon ,  *oxygen heterocyclic compound ,  *nitrogen heterocyclic compound ,  *chemical compound ,  chemical synthesis ,  *stereochemistry ,  *palladium catalyst ,  consecutive reaction ,  cyclization reaction ,  dehydrogenation (chemical reaction) ,  high performance liquid chromatography ,  optical resolution ,  stability ,  density functional method ,  molecular structure ,  helicene ,  *chiral compound ,  cascade reaction ,  chiral high performance liquid chromatography
Semi thesaurus term： domino reaction ,  chiral HPLC ,  DFT calculation

Author keywords (3)： Heterohelicene ,  Benzodiheterole ,  Domino cyclodehydrogenation

JST classification (4)： Condensed tetra-or more-cyclic carbocyclic compounds  (CF06090C) ,  Condensed derivatives of furan  (CF07073M) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Electronic structure of molecules  (BH05010Q)

Substance index (6)： Diacetic acid palladium(II) salt ,  (7)Helicene ,  Oxa[7]helicenen ,  2,1-(Naphthalene-1,2-diyloxy)-3,4-(naphthalene-1,2-diylimino)naphthalene ,  2,1:3,4-Bis[6-methoxynaphthalene-1,2-diyl(tosylimino)]-6,7-dimethylnaphthalene ,  2,1:3,4-Bis(naphthalene-1,2-diylimino)naphthalene

Reference (79)：

• 1) a) M. S. Newman, W. B. Lutz, D. Lednicer, J. Am. Chem. Soc. 1955, 77, 3420.
• 1) b) M. S. Newman, D. Lednicer, J. Am. Chem. Soc. 1956, 78, 4765.
• 2) For recent reviews, see: a) Y. Shen, C.-F. Chen, Chem. Rev. 2012, 112, 1463.
• 2) b) M. Gingras, Chem. Soc. Rev. 2013, 42, 968.
• 2) c) M. Gingras, G. Félix, R. Peresutti, Chem. Soc. Rev. 2013, 42, 1007.

Terms in the title (4)： コア ,  ヘリセン ,  立体 ,  化学的性質