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J-GLOBAL ID：201702212409230241   Reference number：17A0497640

Facile Two-Step Synthesis of 1,10-Phenanthroline-Derived Polyaza[7]helicenes with High Fluorescence and CPL Efficiency

高度の蛍光とCPL効率を持つ1,10-フェナントロリン誘導体ポリアザ[7]ヘリセン類の容易な2段階合成

Author (14)： Otani Takashi (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, 169-8555, Japan) ,  Otani Takashi (Course of Chemical Engineering, National Institute of Technology Anan College, 265 Aoki, Minobayashi, Anan, Tokushima, 774-0017, Japan) ,  Otani Takashi (Research Institute for Science and Technology, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, T, okyo, 162-8601, Japan) ,  Otani Takashi (JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 3, 32-0012, Japan) ,  Tsuyuki Ami (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, 169-8555, Japan) ,  Iwachi Taiki (Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo, 162-8601, Japan) ,  Someya Satoshi (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, 169-8555, Japan) ,  Tateno Kotaro (Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo, 162-8601, Japan) ,  Kawai Hidetoshi (Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo, 162-8601, Japan) ,  Saito Takao (Research Institute for Science and Technology, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, T, okyo, 162-8601, Japan) ,  Saito Takao (Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo, 162-8601, Japan) ,  Kanyiva Kyalo Stephen (International Center for Science and Engineering Programs (ICSEP), Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, 169-8555, Japan) ,  Shibata Takanori (Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku, Tokyo, 169-8555, Japan) ,  Shibata Takanori (JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 3, 32-0012, Japan)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 56  Issue： 14  Page： 3906-3910  Publication year： 2017 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,  *characteristic ,  *polynuclear aromatic hydrocarbon ,  aromatic amine ,  aromatic iodine compound ,  annulation ,  peroxo acid ,  photoluminescence ,  Aniline Compounds ,  circularly polarized luminescence ,  intramolecular cyclization ,  Imidazoles ,  *Phenanthrolines ,  *helicene ,  *fluorescence characteristics
Semi thesaurus term： Imidazoles ,  *phenanthroline derivative ,  *helicenes ,  *fluorescence properties

Author keywords (5)： azahelicene ,  circularly polarized luminescence ,  fluorescence ,  oxidative coupling ,  X-ray diffraction

JST classification (3)： Imidazoles  (CF07083X) ,  Other condensed derivatives of pyridine  (CF07097Y) ,  Aromatic monocyclic halogen compounds  (CF05030H)

Substance index (8)： (aR)-2,2′-(Ethene-1,2-diyl)-1,1′-bi[pyrido[1,2-a]benzoimidazole] ,  (aR)-8,8′-Dimethyl-2,2′-(ethene-1,2-diyl)-1,1′-bi[pyrido[1,2-a]benzoimidazole] ,  (aR)-8,8′-Dimethoxy-2,2′-(ethene-1,2-diyl)-1,1′-bi[pyrido[1,2-a]benzoimidazole] ,  2,9-Dianilino-1,10-phenanthroline ,  3,3′-(Ethene-1,2-diyl)-4a,4′a,8,8′,9,9′-hexaaza-4,4′-bi[4aH-fluorene] ,  3,3′-(Ethene-1,2-diyl)-7,8:7′,8′-di[1,3]butadieno-4a,4′a,9,9′-tetraaza-4,4′-bi[4aH-fluorene] ,  1-Iodo-4-methoxybenzene ,  m-Chloroperbenzoic acid

Terms in the title (5)： 高度 ,  蛍光 ,  フェナントロリン誘導体 ,  ヘリセン類 ,  2段階合成